Organic hydride is considered as one of energy of hydrogen. Hydrogen supplying technology based on organic hydride is now developing in Japan. However, there is no existing study for considering safety of a hydrogen refueling station using organic hydride. The aim of this study is to identify and quantify the human individual risk related to hydrogen explosions and chemical release during the operation of a hydrogen refueling station using organic hydride. As the result, mortality risk by explosion and acute effect was under 10-6 year-1 which is a negligible risk level of concern. However, mortality risk by heat radiation was above 10-3 year-1 which requires a next step to conduct risk assessment in detail.